Wet-chemical synthesis of chiral colloids

Samia Ouhajji; Bas G.P. Van Ravensteijn; Carla Fernández-Rico; Kanvaly S. Lacina; Albert P. Philipse; Andrei V. Petukhov

doi:10.1021/acsnano.8b05065

Wet-chemical synthesis of chiral colloids

Samia Ouhajji^*, Bas G.P. Van Ravensteijn, Carla Fernández-Rico, Kanvaly S. Lacina, Albert P. Philipse, Andrei V. Petukhov

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We disclose a method for the synthesis of chiral colloids from spontaneously formed hollow sugar-surfactant microtubes with internally confined mobile colloidal spheres. Key feature of our approach is the grafting of colloid surfaces with photoresponsive coumarin moieties, which allow for UV-induced, covalent clicking of colloids into permanent chains, with morphologies set by the colloid-to-tube diameter ratio. Subsequent dissolution of tube confinement yields aqueous suspensions that comprise bulk quantities of a variety of linear chains, including single helical chains of polystyrene colloids. These colloidal equivalents of chiral (DNA) molecules are intended for microscopic study of chiral dynamics on a single-particle level.

Original language	English
Pages (from-to)	12089-12095
Journal	ACS Nano
Volume	12
Issue number	12
DOIs	https://doi.org/10.1021/acsnano.8b05065
Publication status	Published - Nov 2018

Keywords

chirality
colloidal synthesis
confined assembly
helices
UV irradiation

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title = "Wet-chemical synthesis of chiral colloids",

abstract = "We disclose a method for the synthesis of chiral colloids from spontaneously formed hollow sugar-surfactant microtubes with internally confined mobile colloidal spheres. Key feature of our approach is the grafting of colloid surfaces with photoresponsive coumarin moieties, which allow for UV-induced, covalent clicking of colloids into permanent chains, with morphologies set by the colloid-to-tube diameter ratio. Subsequent dissolution of tube confinement yields aqueous suspensions that comprise bulk quantities of a variety of linear chains, including single helical chains of polystyrene colloids. These colloidal equivalents of chiral (DNA) molecules are intended for microscopic study of chiral dynamics on a single-particle level.",

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year = "2018",

month = nov,

doi = "10.1021/acsnano.8b05065",

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T1 - Wet-chemical synthesis of chiral colloids

AU - Ouhajji, Samia

AU - Van Ravensteijn, Bas G.P.

AU - Fernández-Rico, Carla

AU - Lacina, Kanvaly S.

AU - Philipse, Albert P.

AU - Petukhov, Andrei V.

PY - 2018/11

Y1 - 2018/11

N2 - We disclose a method for the synthesis of chiral colloids from spontaneously formed hollow sugar-surfactant microtubes with internally confined mobile colloidal spheres. Key feature of our approach is the grafting of colloid surfaces with photoresponsive coumarin moieties, which allow for UV-induced, covalent clicking of colloids into permanent chains, with morphologies set by the colloid-to-tube diameter ratio. Subsequent dissolution of tube confinement yields aqueous suspensions that comprise bulk quantities of a variety of linear chains, including single helical chains of polystyrene colloids. These colloidal equivalents of chiral (DNA) molecules are intended for microscopic study of chiral dynamics on a single-particle level.

AB - We disclose a method for the synthesis of chiral colloids from spontaneously formed hollow sugar-surfactant microtubes with internally confined mobile colloidal spheres. Key feature of our approach is the grafting of colloid surfaces with photoresponsive coumarin moieties, which allow for UV-induced, covalent clicking of colloids into permanent chains, with morphologies set by the colloid-to-tube diameter ratio. Subsequent dissolution of tube confinement yields aqueous suspensions that comprise bulk quantities of a variety of linear chains, including single helical chains of polystyrene colloids. These colloidal equivalents of chiral (DNA) molecules are intended for microscopic study of chiral dynamics on a single-particle level.

KW - chirality

KW - colloidal synthesis

KW - confined assembly

KW - helices

KW - UV irradiation

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DO - 10.1021/acsnano.8b05065

M3 - Article

AN - SCOPUS:85057545323

SN - 1936-0851

VL - 12

SP - 12089

EP - 12095

JO - ACS Nano

JF - ACS Nano

IS - 12

ER -

Wet-chemical synthesis of chiral colloids

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