Vinyl glycosides in oligosaccharide synthesis (part 1): A new latent-active glycosylation strategy

Geert Jan Boons; Stephen Isles

doi:10.1016/S0040-4039(00)73249-7

Vinyl glycosides in oligosaccharide synthesis (part 1): A new latent-active glycosylation strategy

Geert Jan Boons^*, Stephen Isles

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We have developed a novel latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.

Original language	English
Pages (from-to)	3593-3596
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4039(00)73249-7
Publication status	Published - 23 May 1994
Externally published	Yes

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title = "Vinyl glycosides in oligosaccharide synthesis (part 1): A new latent-active glycosylation strategy",

abstract = "We have developed a novel latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.",

author = "Boons, {Geert Jan} and Stephen Isles",

year = "1994",

month = may,

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doi = "10.1016/S0040-4039(00)73249-7",

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T2 - A new latent-active glycosylation strategy

AU - Boons, Geert Jan

AU - Isles, Stephen

PY - 1994/5/23

Y1 - 1994/5/23

N2 - We have developed a novel latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.

AB - We have developed a novel latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.

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U2 - 10.1016/S0040-4039(00)73249-7

DO - 10.1016/S0040-4039(00)73249-7

M3 - Article

AN - SCOPUS:0028241484

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SP - 3593

EP - 3596

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

Vinyl glycosides in oligosaccharide synthesis (part 1): A new latent-active glycosylation strategy

Abstract

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