Abstract
We report on the direct observation of key organic template-framework interactions leading to the formation of specific aluminophosphate structures. In particular, we show how MeAPO-34 formation was governed by an interaction between the divalent framework substituted metal ion and the template conformation, while for AlPO-5 the structure formation was determined by the template conformation alone. Understanding such interactions therefore appears to be important for the rationalization of microporous material formation.
Original language | English |
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Pages (from-to) | 11744-11745 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 128 |
Issue number | 36 |
DOIs | |
Publication status | Published - 13 Sept 2006 |