Unified internal architecture and surface barriers for molecular diffusion of microporous crystalline aluminophosphates

L. Karwacki; H.E. van der Bij; J. Kornatowski; P. Cubillas; M.R. Drury; D.A.M. de Winter; M.W. Anderson; B.M. Weckhuysen

doi:10.1002/anie.201003273

Unified internal architecture and surface barriers for molecular diffusion of microporous crystalline aluminophosphates

L. Karwacki, H.E. van der Bij, J. Kornatowski, P. Cubillas, M.R. Drury, D.A.M. de Winter, M.W. Anderson, B.M. Weckhuysen

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Abstract

Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO-5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star-shaped subcrystal according to studies by CFM, focused ion beam milling, electron backscatter diffraction, and atomic force microscopy.

Original language	English
Pages (from-to)	6790-6794
Number of pages	5
Journal	Angewandte Chemie-International Edition
Volume	49
Issue number	38
DOIs	https://doi.org/10.1002/anie.201003273
Publication status	Published - 2010

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title = "Unified internal architecture and surface barriers for molecular diffusion of microporous crystalline aluminophosphates",

abstract = "Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO-5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star-shaped subcrystal according to studies by CFM, focused ion beam milling, electron backscatter diffraction, and atomic force microscopy.",

author = "L. Karwacki and {van der Bij}, H.E. and J. Kornatowski and P. Cubillas and M.R. Drury and {de Winter}, D.A.M. and M.W. Anderson and B.M. Weckhuysen",

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T1 - Unified internal architecture and surface barriers for molecular diffusion of microporous crystalline aluminophosphates

AU - Karwacki, L.

AU - van der Bij, H.E.

AU - Kornatowski, J.

AU - Cubillas, P.

AU - Drury, M.R.

AU - de Winter, D.A.M.

AU - Anderson, M.W.

AU - Weckhuysen, B.M.

PY - 2010

Y1 - 2010

N2 - Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO-5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star-shaped subcrystal according to studies by CFM, focused ion beam milling, electron backscatter diffraction, and atomic force microscopy.

AB - Starless molecular sieves: The starlike appearence of confocal fluorescence microscopy (CFM) images of large crystals of the AlPO-5 family of microporous materials is due to the presence of barriers to molecular diffusion in the internal crystal architecture (see picture) rather than a star-shaped subcrystal according to studies by CFM, focused ion beam milling, electron backscatter diffraction, and atomic force microscopy.

U2 - 10.1002/anie.201003273

DO - 10.1002/anie.201003273

M3 - Article

SN - 1433-7851

VL - 49

SP - 6790

EP - 6794

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

IS - 38

ER -

Unified internal architecture and surface barriers for molecular diffusion of microporous crystalline aluminophosphates

Abstract

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