TY - JOUR
T1 - Unexpected reactivity of a PONNOP ‘expanded pincer’ ligand
AU - Scheerder, Arthur R.
AU - Lutz, Martin
AU - Broere, Daniël L. J.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform.
AB - We report the synthesis, characterization and coordination chemistry of a new naphthyridine-derived phosphinite PONNOP expanded pincer ligand. As envisioned, the dinucleating ligand readily binds two copper(I) centers in close proximity, but undergoes an unexpected rearrangement in the presence of nickel(II) salts to form an interesting PONNP pincer platform.
UR - https://www.mendeley.com/catalogue/0e03abfc-c713-3c99-98f6-630e63f56099/
U2 - 10.1039/D0CC02166K
DO - 10.1039/D0CC02166K
M3 - Article
C2 - 32395727
SN - 1359-7345
VL - 56
SP - 8198
EP - 8201
JO - Chemical Communications
JF - Chemical Communications
IS - 59
ER -