Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

Claudia M.P Kronenburg; Catelijne H.M Amijs; Peter Wijkens; Johann T.B.H Jastrzebski; Gerard Van Koten

doi:10.1016/S0040-4039(01)02337-1

Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

Claudia M.P Kronenburg, Catelijne H.M Amijs, Peter Wijkens, Johann T.B.H Jastrzebski, Gerard Van Koten

Utrecht University

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C6H4(CH2NMe2)-2]-, 1a) or type CuLi2(CN)Ar2(1b) shows the unexpected formation of aryl-cyanides in up to 30% yield. © 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1113-1115
Number of pages	3
Journal	Tetrahedron Letters
Volume	43
Issue number	6
DOIs	https://doi.org/10.1016/S0040-4039(01)02337-1
Publication status	Published - 4 Feb 2002

Keywords

copper derivative
cyanide
article
decomposition
gas chromatography
ion transport
mass spectrometry
oxidation

Access to Document

10.1016/S0040-4039(01)02337-1

12718
Open Access (free)

Cite this

@article{41890bd8ea9a4a49a55408ca325de90d,

title = "Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?",

abstract = "Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C6H4(CH2NMe2)-2]-, 1a) or type CuLi2(CN)Ar2(1b) shows the unexpected formation of aryl-cyanides in up to 30% yield. {\textcopyright} 2002 Elsevier Science Ltd. All rights reserved.",

keywords = "copper derivative, cyanide, article, decomposition, gas chromatography, ion transport, mass spectrometry, oxidation",

author = "Kronenburg, {Claudia M.P} and Amijs, {Catelijne H.M} and Peter Wijkens and Jastrzebski, {Johann T.B.H} and {Van Koten}, Gerard",

year = "2002",

month = feb,

day = "4",

doi = "10.1016/S0040-4039(01)02337-1",

language = "English",

volume = "43",

pages = "1113--1115",

journal = "Tetrahedron Letters",

issn = "0040-4039",