Abstract
(Matrix Presented) Thioglycosides protected as trans-2,3-cyclic carbonates have significantly lower anomeric reactivities than fully acylated and N-acyl-protected thioglycosides and can be used as acceptors in chemoselective glycosylations with a wide range of thioglycosyl donors. The resulting thioglycosides can be further activated to give 1.2-cis-linked glycosides.
Original language | English |
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Pages (from-to) | 4201-4203 |
Number of pages | 3 |
Journal | Organic Letters |
Volume | 3 |
Issue number | 26 |
DOIs | |
Publication status | Published - 27 Dec 2001 |
Externally published | Yes |