Thioglycosides protected as trans-2,3-cyclic carbonates in chemoselective glycosylations

Tong Zhu, Geert Jan Boons*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

(Matrix Presented) Thioglycosides protected as trans-2,3-cyclic carbonates have significantly lower anomeric reactivities than fully acylated and N-acyl-protected thioglycosides and can be used as acceptors in chemoselective glycosylations with a wide range of thioglycosyl donors. The resulting thioglycosides can be further activated to give 1.2-cis-linked glycosides.

Original languageEnglish
Pages (from-to)4201-4203
Number of pages3
JournalOrganic Letters
Volume3
Issue number26
DOIs
Publication statusPublished - 27 Dec 2001
Externally publishedYes

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