Theoretical Study of Dipolar Relaxation of Coupled Nuclear Spins at Variable Magnetic Field

A.N. Pravdivtsev, K.L. Ivanov, R. Kaptein, A.V. Yurkovskaya

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

A theoretical study was made of magnetic field-dependent dipolar relaxation in two- and three-spin systems. The results for the nuclear magnetic relaxation dispersion (NMRD) curves were compared with those for the simpler model of fluctuating local fields. For both models it was found that at low fields spins tend to relax with a common T1-relaxation time. Sharp features in the NMRD curves coming from nuclear spin level anti-crossings are also predicted by both models. However, the simple model fails to describe the behavior of so-called longlived spin states (LLS). We have studied the LLS as function of magnetic field and molecular geometry and simulated experimental results for the LLS in histidine amino acid obtained at the laboratory of Prof. H.-M. Vieth (Free University Berlin, Germany). In addition, we described polarization transfer in a three-spin system where two spins are protons, which are initially hyperpolarized by para-hydrogen induced polarization (PHIP), while the third spin is a spin hetero-nucleus, which acquires polarization in the course of cross-relaxation.
Original languageEnglish
Pages (from-to)23-39
Number of pages17
JournalApplied Magnetic Resonance
Volume44
DOIs
Publication statusPublished - 2013

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