The role of Mn in the electronic structure of Ba3Ti2MnO9

G Radtke; C Maunders; S Lazar; FMF de Groot; J Etheridge; GA Botton

doi:10.1016/j.jssc.2005.08.020

The role of Mn in the electronic structure of Ba3Ti2MnO9

G Radtke, C Maunders, S Lazar, FMF de Groot, J Etheridge, GA Botton^*

^*Corresponding author for this work

Sub Inorganic Chemistry and Catalysis

Utrecht University

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The energy loss near edge structure (ELNES) of the O-K, Ti-L-23 and Mn-L-23 edges have been recorded in hexagonal Ba(3)Ti(2)NlnO(9) with an energy resolution of 0.10-0.20eV using a monochromator on a commercial transmission electron microscope (TEM) and compared with a tetragonal BaTiO3 reference sample. The formal valency and symmetry of Mn have been determined using atomic multiplets calculations and its effect on the electronic structure of BaTiO3 has been interpreted through a molecular-orbital model. (c) 2005 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	3426-3430
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	178
Issue number	11
DOIs	https://doi.org/10.1016/j.jssc.2005.08.020
Publication status	Published - Nov 2005

Keywords

energy loss near edge fine structure
transition metal oxide
hexagonal perovskite
electronic structure
X-RAY-ABSORPTION
ENERGY-LOSS SPECTROSCOPY
TRANSITION-METAL OXIDES
MANGANESE OXIDES
EDGE STRUCTURES
CUBIC BATIO3
SUBSTITUTION
MINERALS
TITANIUM
CRYSTAL

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10.1016/j.jssc.2005.08.020

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title = "The role of Mn in the electronic structure of Ba3Ti2MnO9",

abstract = "The energy loss near edge structure (ELNES) of the O-K, Ti-L-23 and Mn-L-23 edges have been recorded in hexagonal Ba(3)Ti(2)NlnO(9) with an energy resolution of 0.10-0.20eV using a monochromator on a commercial transmission electron microscope (TEM) and compared with a tetragonal BaTiO3 reference sample. The formal valency and symmetry of Mn have been determined using atomic multiplets calculations and its effect on the electronic structure of BaTiO3 has been interpreted through a molecular-orbital model. (c) 2005 Elsevier Inc. All rights reserved.",

keywords = "energy loss near edge fine structure, transition metal oxide, hexagonal perovskite, electronic structure, X-RAY-ABSORPTION, ENERGY-LOSS SPECTROSCOPY, TRANSITION-METAL OXIDES, MANGANESE OXIDES, EDGE STRUCTURES, CUBIC BATIO3, SUBSTITUTION, MINERALS, TITANIUM, CRYSTAL",

author = "G Radtke and C Maunders and S Lazar and {de Groot}, FMF and J Etheridge and GA Botton",

year = "2005",

month = nov,

doi = "10.1016/j.jssc.2005.08.020",

language = "English",

volume = "178",

pages = "3426--3430",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - The role of Mn in the electronic structure of Ba3Ti2MnO9

AU - Radtke, G

AU - Maunders, C

AU - Lazar, S

AU - de Groot, FMF

AU - Etheridge, J

AU - Botton, GA

PY - 2005/11

Y1 - 2005/11

N2 - The energy loss near edge structure (ELNES) of the O-K, Ti-L-23 and Mn-L-23 edges have been recorded in hexagonal Ba(3)Ti(2)NlnO(9) with an energy resolution of 0.10-0.20eV using a monochromator on a commercial transmission electron microscope (TEM) and compared with a tetragonal BaTiO3 reference sample. The formal valency and symmetry of Mn have been determined using atomic multiplets calculations and its effect on the electronic structure of BaTiO3 has been interpreted through a molecular-orbital model. (c) 2005 Elsevier Inc. All rights reserved.

AB - The energy loss near edge structure (ELNES) of the O-K, Ti-L-23 and Mn-L-23 edges have been recorded in hexagonal Ba(3)Ti(2)NlnO(9) with an energy resolution of 0.10-0.20eV using a monochromator on a commercial transmission electron microscope (TEM) and compared with a tetragonal BaTiO3 reference sample. The formal valency and symmetry of Mn have been determined using atomic multiplets calculations and its effect on the electronic structure of BaTiO3 has been interpreted through a molecular-orbital model. (c) 2005 Elsevier Inc. All rights reserved.

KW - energy loss near edge fine structure

KW - transition metal oxide

KW - hexagonal perovskite

KW - electronic structure

KW - X-RAY-ABSORPTION

KW - ENERGY-LOSS SPECTROSCOPY

KW - TRANSITION-METAL OXIDES

KW - MANGANESE OXIDES

KW - EDGE STRUCTURES

KW - CUBIC BATIO3

KW - SUBSTITUTION

KW - MINERALS

KW - TITANIUM

KW - CRYSTAL

U2 - 10.1016/j.jssc.2005.08.020

DO - 10.1016/j.jssc.2005.08.020

M3 - Article

SN - 0022-4596

VL - 178

SP - 3426

EP - 3430

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 11

ER -

The role of Mn in the electronic structure of Ba3Ti2MnO9

Abstract

Keywords

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