Terrestrial acidification during the end-Permian biosphere crisis?

Excessive acid rainfall associated with emplacement of the Siberian Traps magmatic province is increasingly accepted as a major contributing factor to the end-Permian biosphere crisis. However, direct proxy evidence of terrestrial acidification is so far not available. In this paper, we seek to determine the probability that relative proportions of extractable monophe- nolic components from soil-derived organic matter in marine sediments provide a molecular proxy for estimating soil acidity. Intermittently low and high ratios of vanillic acid to vanillin detected in latest Permian and earliest Triassic deposits of the southern Alps, Italy, support concepts of pulses of severe acidification (pH <4) during the main phase of the biosphere crisis.