Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

Marc-Etienne Moret; Jonas C. Peters

doi:10.1002/anie.201006918

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

Marc-Etienne Moret, Jonas C. Peters^*

^*Corresponding author for this work

California Institute of Technology

Research output: Contribution to journal › Article › Academic › peer-review

Original language	English
Pages (from-to)	2063-2067
Number of pages	5
Journal	Angewandte Chemie-International Edition
Volume	50
Issue number	9
DOIs	https://doi.org/10.1002/anie.201006918
Publication status	Published - 2011
Externally published	Yes

Funding

This work was supported by the NIH (GM 070757). M.-E.M. acknowledges a Fellowship for Prospective Researchers from the Swiss National Science Foundation. We thank Charlene Tsay and Larry Henling for crystallographic assistance, as well as David VanderVelde for assistance with DOSY experiments and Angelo Di Bilio for EPR measurements.

Keywords

iron
metallaboratranes
multiple bonds
nitrogen fixation
phosphinoborane ligands
DATIVE SIGMA-BOND
STRUCTURAL-CHARACTERIZATION
CATALYTIC-REDUCTION
NITROGEN-FIXATION
NITRIDO COMPLEX
FE-IVN
BORANE
METALLABORATRANES
REACTIVITY
AMMONIA

Access to Document

10.1002/anie.201006918

Cite this

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title = "Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand",

keywords = "iron, metallaboratranes, multiple bonds, nitrogen fixation, phosphinoborane ligands, DATIVE SIGMA-BOND, STRUCTURAL-CHARACTERIZATION, CATALYTIC-REDUCTION, NITROGEN-FIXATION, NITRIDO COMPLEX, FE-IVN, BORANE, METALLABORATRANES, REACTIVITY, AMMONIA",

author = "Marc-Etienne Moret and Peters, {Jonas C.}",

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T1 - Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

AU - Moret, Marc-Etienne

AU - Peters, Jonas C.

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Y1 - 2011

KW - iron

KW - metallaboratranes

KW - multiple bonds

KW - nitrogen fixation

KW - phosphinoborane ligands

KW - DATIVE SIGMA-BOND

KW - STRUCTURAL-CHARACTERIZATION

KW - CATALYTIC-REDUCTION

KW - NITROGEN-FIXATION

KW - NITRIDO COMPLEX

KW - FE-IVN

KW - BORANE

KW - METALLABORATRANES

KW - REACTIVITY

KW - AMMONIA

U2 - 10.1002/anie.201006918

DO - 10.1002/anie.201006918

M3 - Article

SN - 1433-7851

VL - 50

SP - 2063

EP - 2067

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

IS - 9

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