Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

O.F. Göbel; J.E. ten Elshof; A.M.M. Schreurs

Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

O.F. Göbel, J.E. ten Elshof, A.M.M. Schreurs

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The crystal structure of (TMA)2[TiF6] between -173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures.

Original language	English
Pages (from-to)	748-755
Number of pages	8
Journal	Zeitschrift fur Kristallographie
Volume	226
Issue number	9
Publication status	Published - 2011

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title = "Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]",

abstract = "The crystal structure of (TMA)2[TiF6] between -173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures.",

author = "O.F. G{\"o}bel and {ten Elshof}, J.E. and A.M.M. Schreurs",

year = "2011",

language = "English",

volume = "226",

pages = "748--755",

journal = "Zeitschrift fur Kristallographie",

issn = "0044-2968",

publisher = "Walter de Gruyter GmbH",

number = "9",

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TY - JOUR

T1 - Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

AU - Göbel, O.F.

AU - ten Elshof, J.E.

AU - Schreurs, A.M.M.

PY - 2011

Y1 - 2011

N2 - The crystal structure of (TMA)2[TiF6] between -173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures.

AB - The crystal structure of (TMA)2[TiF6] between -173 °C and 180 °C was refined on the basis of single crystal diffraction data. A phase transition from rhombohedral to cubic at approx. 142 °C was found by measuring the birefringence as a function of temperature, and confirmed by the refined crystal structures.

M3 - Article

SN - 0044-2968

VL - 226

SP - 748

EP - 755

JO - Zeitschrift fur Kristallographie

JF - Zeitschrift fur Kristallographie

IS - 9

ER -

Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate(IV), (TMA)2[TiF6]

Abstract

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