Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Regina Palkovits; Andrei N. Parvulescu; Peter J. C. Hausoul; Cornelis A. Kruithof; Robertus J. M. Klein Gebbink; Bert M. Weckhuysen

doi:10.1039/b904274a

Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Regina Palkovits
, Andrei N. Parvulescu
, Peter J. C. Hausoul
, Cornelis A. Kruithof
, Robertus J. M. Klein Gebbink
, Bert M. Weckhuysen

Utrecht University of Applied Sciences

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The telomerization of 1,3-butadiene with various alcohols has been investigated using a catalyst based on a Pd(acac)(2) precursor and a phosphine ligand, TOMPP (TOMPP = tris-(o-methoxyphenyl)phosphine). We were able to demonstrate the capability of the catalyst to telomerize 1,3-butadiene with various multifunctional nucleophiles having primary and secondary alcohol functions. High yields of telomer products (>98%) were obtained in very short reaction times (

Original language	English
Pages (from-to)	1155-1160
Number of pages	6
Journal	Green Chemistry
Volume	11
Issue number	8
DOIs	https://doi.org/10.1039/b904274a
Publication status	Published - 2009

Keywords

Palladium catalysts
Convenient route
Fine chemicals
Butadiene
Efficient
Glycerol
Sucrose
Ligands
Hydrogenation
Dimerization

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10.1039/b904274a

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T2 - new opportunities for catalytic biomass valorization

AU - Palkovits, Regina

AU - Parvulescu, Andrei N.

AU - Hausoul, Peter J. C.

AU - Kruithof, Cornelis A.

AU - Gebbink, Robertus J. M. Klein

AU - Weckhuysen, Bert M.

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KW - Palladium catalysts

KW - Convenient route

KW - Fine chemicals

KW - Butadiene

KW - Efficient

KW - Glycerol

KW - Sucrose

KW - Ligands

KW - Hydrogenation

KW - Dimerization

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Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

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