Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Regina Palkovits; Andrei N. Parvulescu; Peter J. C. Hausoul; Cornelis A. Kruithof; Robertus J. M. Klein Gebbink; Bert M. Weckhuysen

doi:10.1039/b904274a

Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Regina Palkovits, Andrei N. Parvulescu, Peter J. C. Hausoul, Cornelis A. Kruithof, Robertus J. M. Klein Gebbink, Bert M. Weckhuysen

Utrecht University of Applied Sciences

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The telomerization of 1,3-butadiene with various alcohols has been investigated using a catalyst based on a Pd(acac)(2) precursor and a phosphine ligand, TOMPP (TOMPP = tris-(o-methoxyphenyl)phosphine). We were able to demonstrate the capability of the catalyst to telomerize 1,3-butadiene with various multifunctional nucleophiles having primary and secondary alcohol functions. High yields of telomer products (>98%) were obtained in very short reaction times (

Original language	English
Pages (from-to)	1155-1160
Number of pages	6
Journal	Green Chemistry
Volume	11
Issue number	8
DOIs	https://doi.org/10.1039/b904274a
Publication status	Published - 2009

Keywords

Palladium catalysts
Convenient route
Fine chemicals
Butadiene
Efficient
Glycerol
Sucrose
Ligands
Hydrogenation
Dimerization

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AU - Palkovits, Regina

AU - Parvulescu, Andrei N.

AU - Hausoul, Peter J. C.

AU - Kruithof, Cornelis A.

AU - Gebbink, Robertus J. M. Klein

AU - Weckhuysen, Bert M.

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KW - Palladium catalysts

KW - Convenient route

KW - Fine chemicals

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KW - Glycerol

KW - Sucrose

KW - Ligands

KW - Hydrogenation

KW - Dimerization

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Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Abstract

Keywords

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