T-shaped cationic cu complexes with hemilabile pnp-type ligands

J.I. van der Vlugt; E.A. Pidko; D. Vogt; M. Lutz; A.L. Spek; A. Meetsma

T-shaped cationic cu complexes with hemilabile pnp-type ligands

J.I. van der Vlugt, E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek, A. Meetsma

Dept of Chemistry

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The versatile coordination behavior of the PNP ligands 1A (2,6- bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino) methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

Original language	Undefined/Unknown
Pages (from-to)	4442-4444
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Publication status	Published - 2008

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Cite this

@article{56228f394eff46768871d2261d854533,

title = "T-shaped cationic cu complexes with hemilabile pnp-type ligands",

abstract = "The versatile coordination behavior of the PNP ligands 1A (2,6- bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino) methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.",

author = "{van der Vlugt}, J.I. and E.A. Pidko and D. Vogt and M. Lutz and A.L. Spek and A. Meetsma",

year = "2008",

language = "Undefined/Unknown",

volume = "47",

pages = "4442--4444",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - T-shaped cationic cu complexes with hemilabile pnp-type ligands

AU - van der Vlugt, J.I.

AU - Pidko, E.A.

AU - Vogt, D.

AU - Lutz, M.

AU - Spek, A.L.

AU - Meetsma, A.

PY - 2008

Y1 - 2008

N2 - The versatile coordination behavior of the PNP ligands 1A (2,6- bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino) methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

AB - The versatile coordination behavior of the PNP ligands 1A (2,6- bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino) methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

M3 - Article

SN - 0020-1669

VL - 47

SP - 4442

EP - 4444

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -