Synthesis of poly(meta-diethynyl benzene) with initiated chemical vapour deposition

R. Bakker; P. Weijers; D.A. Spee; M.J. van Steenbergen; C.H.M. van der Werf; J.K. Rath; R.E.I. Schropp

doi:10.1016/j.tsf.2011.01.310

Synthesis of poly(meta-diethynyl benzene) with initiated chemical vapour deposition

R. Bakker, P. Weijers, D.A. Spee, M.J. van Steenbergen, C.H.M. van der Werf, J.K. Rath, R.E.I. Schropp

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

In this work, polymerization of meta-diethynyl benzene (MDEB) using iCVD is reported, which opens possibilities for use of polymers as a dielectric insulator in electronic applications that cannot be combined with solvent-based materials. iCVD is a solvent free production method, allowing the deposition of PMDEB layers at a rate of 12 nm/min. The polymers produced have a high molecular weight with a broad distribution (1000 to more than 25,000 g/mole) and a clearly defined Fourier transform infrared spectrum. The presence of a small peak at 2105 cm−1 and a monomer peak in the gel permeation chromatogram (GPC) suggest that that some monomer is incorporated in the layers.

Original language	English
Pages (from-to)	4418-4420
Number of pages	3
Journal	Thin Solid Films
Volume	519
Issue number	14
DOIs	https://doi.org/10.1016/j.tsf.2011.01.310
Publication status	Published - 2011

Keywords

Farmacie/Biofarmaceutische wetenschappen (FARM)
Medical technology
Farmacie(FARM)
Biomedische technologie en medicijnen
Pharmacology

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10.1016/j.tsf.2011.01.310

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title = "Synthesis of poly(meta-diethynyl benzene) with initiated chemical vapour deposition",

abstract = "In this work, polymerization of meta-diethynyl benzene (MDEB) using iCVD is reported, which opens possibilities for use of polymers as a dielectric insulator in electronic applications that cannot be combined with solvent-based materials. iCVD is a solvent free production method, allowing the deposition of PMDEB layers at a rate of 12 nm/min. The polymers produced have a high molecular weight with a broad distribution (1000 to more than 25,000 g/mole) and a clearly defined Fourier transform infrared spectrum. The presence of a small peak at 2105 cm−1 and a monomer peak in the gel permeation chromatogram (GPC) suggest that that some monomer is incorporated in the layers.",

keywords = "Farmacie/Biofarmaceutische wetenschappen (FARM), Medical technology, Farmacie(FARM), Biomedische technologie en medicijnen, Pharmacology",

author = "R. Bakker and P. Weijers and D.A. Spee and {van Steenbergen}, M.J. and {van der Werf}, C.H.M. and J.K. Rath and R.E.I. Schropp",

year = "2011",

doi = "10.1016/j.tsf.2011.01.310",

language = "English",

volume = "519",

pages = "4418--4420",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier BV",

number = "14",

}

TY - JOUR

T1 - Synthesis of poly(meta-diethynyl benzene) with initiated chemical vapour deposition

AU - Bakker, R.

AU - Weijers, P.

AU - Spee, D.A.

AU - van Steenbergen, M.J.

AU - van der Werf, C.H.M.

AU - Rath, J.K.

AU - Schropp, R.E.I.

PY - 2011

Y1 - 2011

N2 - In this work, polymerization of meta-diethynyl benzene (MDEB) using iCVD is reported, which opens possibilities for use of polymers as a dielectric insulator in electronic applications that cannot be combined with solvent-based materials. iCVD is a solvent free production method, allowing the deposition of PMDEB layers at a rate of 12 nm/min. The polymers produced have a high molecular weight with a broad distribution (1000 to more than 25,000 g/mole) and a clearly defined Fourier transform infrared spectrum. The presence of a small peak at 2105 cm−1 and a monomer peak in the gel permeation chromatogram (GPC) suggest that that some monomer is incorporated in the layers.

AB - In this work, polymerization of meta-diethynyl benzene (MDEB) using iCVD is reported, which opens possibilities for use of polymers as a dielectric insulator in electronic applications that cannot be combined with solvent-based materials. iCVD is a solvent free production method, allowing the deposition of PMDEB layers at a rate of 12 nm/min. The polymers produced have a high molecular weight with a broad distribution (1000 to more than 25,000 g/mole) and a clearly defined Fourier transform infrared spectrum. The presence of a small peak at 2105 cm−1 and a monomer peak in the gel permeation chromatogram (GPC) suggest that that some monomer is incorporated in the layers.

KW - Farmacie/Biofarmaceutische wetenschappen (FARM)

KW - Medical technology

KW - Farmacie(FARM)

KW - Biomedische technologie en medicijnen

KW - Pharmacology

U2 - 10.1016/j.tsf.2011.01.310

DO - 10.1016/j.tsf.2011.01.310

M3 - Article

SN - 0040-6090

VL - 519

SP - 4418

EP - 4420

JO - Thin Solid Films

JF - Thin Solid Films

IS - 14

ER -

Synthesis of poly(meta-diethynyl benzene) with initiated chemical vapour deposition

Abstract

Keywords

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