Synthesis of 4-functionalized terdendate pyridine-based ligands

T Vermonden; D Branowska; ATM Marcelis; EJR Sudholter

doi:10.1016/S0040-4020(03)00753-1

Synthesis of 4-functionalized terdendate pyridine-based ligands

T Vermonden
, D Branowska
, ATM Marcelis^*
, EJR Sudholter

^*Corresponding author for this work

Pharmaceutics

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.

Original language	English
Pages (from-to)	5039-5045
Number of pages	7
Journal	Tetrahedron
Volume	59
Issue number	27
DOIs	https://doi.org/10.1016/S0040-4020(03)00753-1
Publication status	Published - 30 Jun 2003

Keywords

terdendate
ligand
coordination
supramolecular
surfactant
RUTHENIUM(II) COMPLEXES
COORDINATION POLYMERS
OLIGOPYRIDINES
LANTHANIDE
CHEMISTRY
ANALOGS

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title = "Synthesis of 4-functionalized terdendate pyridine-based ligands",

abstract = "Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.",

keywords = "terdendate, ligand, coordination, supramolecular, surfactant, RUTHENIUM(II) COMPLEXES, COORDINATION POLYMERS, OLIGOPYRIDINES, LANTHANIDE, CHEMISTRY, ANALOGS",

author = "T Vermonden and D Branowska and ATM Marcelis and EJR Sudholter",

year = "2003",

month = jun,

day = "30",

doi = "10.1016/S0040-4020(03)00753-1",

language = "English",

volume = "59",

pages = "5039--5045",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "27",

}

TY - JOUR

T1 - Synthesis of 4-functionalized terdendate pyridine-based ligands

AU - Vermonden, T

AU - Branowska, D

AU - Marcelis, ATM

AU - Sudholter, EJR

PY - 2003/6/30

Y1 - 2003/6/30

N2 - Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.

AB - Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.

KW - terdendate

KW - ligand

KW - coordination

KW - supramolecular

KW - surfactant

KW - RUTHENIUM(II) COMPLEXES

KW - COORDINATION POLYMERS

KW - OLIGOPYRIDINES

KW - LANTHANIDE

KW - CHEMISTRY

KW - ANALOGS

U2 - 10.1016/S0040-4020(03)00753-1

DO - 10.1016/S0040-4020(03)00753-1

M3 - Article

SN - 0040-4020

VL - 59

SP - 5039

EP - 5045

JO - Tetrahedron

JF - Tetrahedron

IS - 27

ER -

Synthesis of 4-functionalized terdendate pyridine-based ligands

Abstract

Keywords

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