Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2

Evelien Rijnberg; Johann T B H Jastrzebski; Jaap Boersma; Huub Kooijman; Anthony L. Spek; Gerard Van Koten

Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) ₆[Zn(CH₂Ph)₃]₂

Evelien Rijnberg, Johann T B H Jastrzebski, Jaap Boersma, Huub Kooijman, Anthony L. Spek, Gerard Van Koten^*

^*Corresponding author for this work

Utrecht University

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The addition of Mg(CH₂Ph)₂(thf)₂ to a thf solution of Zn(CH₂Ph)₂ yields the zincate complex Mg(thf)₆[Zn(CH₂Ph)₃]₂ (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH₂Ph)₂(tmeda) and Zn(CH₂Ph)₂(tmeda).

Original language	English
Pages (from-to)	181-185
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	541
Issue number	1-2
Publication status	Published - 15 Aug 1997

Keywords

Anionic complex
Magnesium
Organozinc
Zincate

Cite this

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title = "Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2",

abstract = "The addition of Mg(CH2Ph)2(thf)2 to a thf solution of Zn(CH2Ph)2 yields the zincate complex Mg(thf)6[Zn(CH2Ph)3]2 (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH2Ph)2(tmeda) and Zn(CH2Ph)2(tmeda).",

keywords = "Anionic complex, Magnesium, Organozinc, Zincate",

author = "Evelien Rijnberg and Jastrzebski, {Johann T B H} and Jaap Boersma and Huub Kooijman and Spek, {Anthony L.} and {Van Koten}, Gerard",

year = "1997",

month = aug,

day = "15",

language = "English",

volume = "541",

pages = "181--185",

journal = "Journal of Organometallic Chemistry",

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T1 - Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2

AU - Rijnberg, Evelien

AU - Jastrzebski, Johann T B H

AU - Boersma, Jaap

AU - Kooijman, Huub

AU - Spek, Anthony L.

AU - Van Koten, Gerard

PY - 1997/8/15

Y1 - 1997/8/15

N2 - The addition of Mg(CH2Ph)2(thf)2 to a thf solution of Zn(CH2Ph)2 yields the zincate complex Mg(thf)6[Zn(CH2Ph)3]2 (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH2Ph)2(tmeda) and Zn(CH2Ph)2(tmeda).

AB - The addition of Mg(CH2Ph)2(thf)2 to a thf solution of Zn(CH2Ph)2 yields the zincate complex Mg(thf)6[Zn(CH2Ph)3]2 (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH2Ph)2(tmeda) and Zn(CH2Ph)2(tmeda).

KW - Anionic complex

KW - Magnesium

KW - Organozinc

KW - Zincate

UR - http://www.scopus.com/inward/record.url?scp=0031571488&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0031571488

SN - 0022-328X

VL - 541

SP - 181

EP - 185

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) ₆[Zn(CH₂Ph)₃]₂

Abstract

Keywords

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