Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands

S.A. Bonnet; J. Li; M.A.M. Siegler; L.S. von Chrzanowski; A.L. Spek; G. van Koten; R.J.M. Klein Gebbink

Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands

S.A. Bonnet, J. Li, M.A.M. Siegler, L.S. von Chrzanowski, A.L. Spek, G. van Koten, R.J.M. Klein Gebbink

Dept of Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on 6,1-coordinated ECE pincer ligands are synthesized as racemic mixtures by reacting ECE-palladium complexes and [Ru(C5R5)(MeCN)3]+ arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [-TRISPHAT]-, and solving the X-ray crystal structure of one diastereoisomer

Original language	Undefined/Unknown
Pages (from-to)	3340-3343
Number of pages	4
Journal	Chemistry-A European Journal
Volume	15
Issue number	14
Publication status	Published - 2009

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title = "Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands",

abstract = "Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on 6,1-coordinated ECE pincer ligands are synthesized as racemic mixtures by reacting ECE-palladium complexes and [Ru(C5R5)(MeCN)3]+ arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [-TRISPHAT]-, and solving the X-ray crystal structure of one diastereoisomer",

author = "S.A. Bonnet and J. Li and M.A.M. Siegler and {von Chrzanowski}, L.S. and A.L. Spek and {van Koten}, G. and {Klein Gebbink}, R.J.M.",

year = "2009",

language = "Undefined/Unknown",

volume = "15",

pages = "3340--3343",

journal = "Chemistry-A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "14",

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T1 - Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands

AU - Bonnet, S.A.

AU - Li, J.

AU - Siegler, M.A.M.

AU - von Chrzanowski, L.S.

AU - Spek, A.L.

AU - van Koten, G.

AU - Klein Gebbink, R.J.M.

PY - 2009

Y1 - 2009

N2 - Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on 6,1-coordinated ECE pincer ligands are synthesized as racemic mixtures by reacting ECE-palladium complexes and [Ru(C5R5)(MeCN)3]+ arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [-TRISPHAT]-, and solving the X-ray crystal structure of one diastereoisomer

AB - Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on 6,1-coordinated ECE pincer ligands are synthesized as racemic mixtures by reacting ECE-palladium complexes and [Ru(C5R5)(MeCN)3]+ arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [-TRISPHAT]-, and solving the X-ray crystal structure of one diastereoisomer

M3 - Article

SN - 0947-6539

VL - 15

SP - 3340

EP - 3343

JO - Chemistry-A European Journal

JF - Chemistry-A European Journal

IS - 14

ER -