Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand

E.J. Farrington; E. Martinez Viviente; S.R. Williams; G. van Koten; J.M. Brown

doi:10.1039/B108585A

Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand

E.J. Farrington, E. Martinez Viviente, S.R. Williams, G. van Koten, J.M. Brown

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the ferrocene.

Original language	English
Pages (from-to)	308-309
Number of pages	2
Journal	Chemical Communications
Volume	2002
Issue number	4
DOIs	https://doi.org/10.1039/B108585A
Publication status	Published - 2002

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title = "Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand",

abstract = "The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the ferrocene.",

author = "E.J. Farrington and {Martinez Viviente}, E. and S.R. Williams and {van Koten}, G. and J.M. Brown",

year = "2002",

doi = "10.1039/B108585A",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Martinez Viviente, E.

AU - Williams, S.R.

AU - van Koten, G.

AU - Brown, J.M.

PY - 2002

Y1 - 2002

N2 - The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the ferrocene.

AB - The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C–H insertion into the ferrocene.

U2 - 10.1039/B108585A

DO - 10.1039/B108585A

M3 - Article

SN - 1359-7345

VL - 2002

SP - 308

EP - 309

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand

Abstract

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