Stable tetranuclear 4-tolyl-copperlithium ("cuprate") and -goldlithium ("aurate") compounds

Gerard van Koten; Johan T B H Jastrzebski; Jan G. Noltes

doi:10.1016/S0022-328X(00)93202-9

Stable tetranuclear 4-tolyl-copperlithium ("cuprate") and -goldlithium ("aurate") compounds

Gerard van Koten^*, Johan T B H Jastrzebski, Jan G. Noltes

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Di-4-tolyl-copperlithium and -goldlithium moncetherate are stable tetranuclear species, with 4-Tol₄M₂Li₂·2 Et₂O stoichiometry, in which the four 4-tolyl groups each bridge one Group IB metal and one lithium atom while each lithium atom further coordinates with one ether molecule.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	140
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)93202-9
Publication status	Published - 1 Nov 1977
Externally published	Yes

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title = "Stable tetranuclear 4-tolyl-copperlithium ({"}cuprate{"}) and -goldlithium ({"}aurate{"}) compounds",

abstract = "Di-4-tolyl-copperlithium and -goldlithium moncetherate are stable tetranuclear species, with 4-Tol4M2Li2·2 Et2O stoichiometry, in which the four 4-tolyl groups each bridge one Group IB metal and one lithium atom while each lithium atom further coordinates with one ether molecule.",

author = "{van Koten}, Gerard and Jastrzebski, {Johan T B H} and Noltes, {Jan G.}",

year = "1977",

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language = "English",

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journal = "Journal of Organometallic Chemistry",

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AU - van Koten, Gerard

AU - Jastrzebski, Johan T B H

AU - Noltes, Jan G.

PY - 1977/11/1

Y1 - 1977/11/1

N2 - Di-4-tolyl-copperlithium and -goldlithium moncetherate are stable tetranuclear species, with 4-Tol4M2Li2·2 Et2O stoichiometry, in which the four 4-tolyl groups each bridge one Group IB metal and one lithium atom while each lithium atom further coordinates with one ether molecule.

AB - Di-4-tolyl-copperlithium and -goldlithium moncetherate are stable tetranuclear species, with 4-Tol4M2Li2·2 Et2O stoichiometry, in which the four 4-tolyl groups each bridge one Group IB metal and one lithium atom while each lithium atom further coordinates with one ether molecule.

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U2 - 10.1016/S0022-328X(00)93202-9

DO - 10.1016/S0022-328X(00)93202-9

M3 - Article

AN - SCOPUS:0005664777

SN - 0022-328X

VL - 140

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Stable tetranuclear 4-tolyl-copperlithium ("cuprate") and -goldlithium ("aurate") compounds

Abstract

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