SOFT-X-RAY-ABSORPTION STUDIES OF THE ELECTRONIC-STRUCTURE CHANGES THROUGH THE VO2 PHASE-TRANSITION

M ABBATE; FMF DEGROOT; JC FUGGLE; YJ MA; CT CHEN; F SETTE; A FUJIMORI; Y UEDA; K KOSUGE; Frank de Groot

SOFT-X-RAY-ABSORPTION STUDIES OF THE ELECTRONIC-STRUCTURE CHANGES THROUGH THE VO2 PHASE-TRANSITION

M ABBATE^*, FMF DEGROOT, JC FUGGLE, YJ MA, CT CHEN, F SETTE, A FUJIMORI, Y UEDA, K KOSUGE, Frank de Groot

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We present the O 1s and V 2p absorption edges of VO2 at room temperature and at T = 120-degrees-C, i.e., below and above the metal-insulator transition temperature T(c) almost-equal-to 67-degrees-C. The O 1s spectra show a clear splitting of 1 eV in the unoccupied d-parallel-to band below T(c). Because the V 2p absorption edges are dominated by the V 2p-3d interaction in the final state, these spectra show minor changes that cannot be easily correlated with the changes in the unoccupied density of states.

Original language	English
Pages (from-to)	7263-7267
Number of pages	5
Journal	Physical review. B, condensed matter
Volume	43
Issue number	9
Publication status	Published - 15 Mar 1991
Externally published	Yes

Keywords

METALLIC VO2
OXIDES
SPECTROSCOPY
ENERGY
MONOCHROMATORS
PHOTOELECTRON
INSULATOR
SPECTRA
LINES
NBO2

Cite this

@article{59542378f087401fbcb617a820c4ec81,

title = "SOFT-X-RAY-ABSORPTION STUDIES OF THE ELECTRONIC-STRUCTURE CHANGES THROUGH THE VO2 PHASE-TRANSITION",

abstract = "We present the O 1s and V 2p absorption edges of VO2 at room temperature and at T = 120-degrees-C, i.e., below and above the metal-insulator transition temperature T(c) almost-equal-to 67-degrees-C. The O 1s spectra show a clear splitting of 1 eV in the unoccupied d-parallel-to band below T(c). Because the V 2p absorption edges are dominated by the V 2p-3d interaction in the final state, these spectra show minor changes that cannot be easily correlated with the changes in the unoccupied density of states.",

keywords = "METALLIC VO2, OXIDES, SPECTROSCOPY, ENERGY, MONOCHROMATORS, PHOTOELECTRON, INSULATOR, SPECTRA, LINES, NBO2",

author = "M ABBATE and FMF DEGROOT and JC FUGGLE and YJ MA and CT CHEN and F SETTE and A FUJIMORI and Y UEDA and K KOSUGE and {de Groot}, Frank",

year = "1991",

month = mar,

day = "15",

language = "English",

volume = "43",

pages = "7263--7267",

journal = "Physical review. B, condensed matter",

issn = "0163-1829",

publisher = "American Institute of Physics",

number = "9",

}

TY - JOUR

T1 - SOFT-X-RAY-ABSORPTION STUDIES OF THE ELECTRONIC-STRUCTURE CHANGES THROUGH THE VO2 PHASE-TRANSITION

AU - ABBATE, M

AU - DEGROOT, FMF

AU - FUGGLE, JC

AU - MA, YJ

AU - CHEN, CT

AU - SETTE, F

AU - FUJIMORI, A

AU - UEDA, Y

AU - KOSUGE, K

AU - de Groot, Frank

PY - 1991/3/15

Y1 - 1991/3/15

N2 - We present the O 1s and V 2p absorption edges of VO2 at room temperature and at T = 120-degrees-C, i.e., below and above the metal-insulator transition temperature T(c) almost-equal-to 67-degrees-C. The O 1s spectra show a clear splitting of 1 eV in the unoccupied d-parallel-to band below T(c). Because the V 2p absorption edges are dominated by the V 2p-3d interaction in the final state, these spectra show minor changes that cannot be easily correlated with the changes in the unoccupied density of states.

AB - We present the O 1s and V 2p absorption edges of VO2 at room temperature and at T = 120-degrees-C, i.e., below and above the metal-insulator transition temperature T(c) almost-equal-to 67-degrees-C. The O 1s spectra show a clear splitting of 1 eV in the unoccupied d-parallel-to band below T(c). Because the V 2p absorption edges are dominated by the V 2p-3d interaction in the final state, these spectra show minor changes that cannot be easily correlated with the changes in the unoccupied density of states.

KW - METALLIC VO2

KW - OXIDES

KW - SPECTROSCOPY

KW - ENERGY

KW - MONOCHROMATORS

KW - PHOTOELECTRON

KW - INSULATOR

KW - SPECTRA

KW - LINES

KW - NBO2

M3 - Article

SN - 0163-1829

VL - 43

SP - 7263

EP - 7267

JO - Physical review. B, condensed matter

JF - Physical review. B, condensed matter

IS - 9

ER -

SOFT-X-RAY-ABSORPTION STUDIES OF THE ELECTRONIC-STRUCTURE CHANGES THROUGH THE VO2 PHASE-TRANSITION

Abstract

Keywords

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