Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters

Yong Guo*, Bas G.P. van Ravensteijn, Willem K. Kegel

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

We report the (spontaneous) formation of colloidal strings, Bernal spiral-like, and tubular clusters comprising spherical, isotropically functionalized colloidal particles in an aqueous environment. The formation of colloidal strings and Bernal spiral-like clusters is guided by an interplay between short-ranged hydrophobic attraction and relatively longer-ranged electrostatic repulsion acting between the colloids. When a dispersion of these colloids is densifiedviacentrifugation, well-defined tubular aggregates were observed.

Original languageEnglish
Pages (from-to)6309-6312
Number of pages4
JournalChemical Communications
Volume56
Issue number46
DOIs
Publication statusPublished - 11 Jun 2020

Bibliographical note

Funding Information:
Y. Guo is supported by Chinese Scholarship council (File No. 201306200056). Kanvaly Lacina, Hans Meeldijk and Chris Schneijdenberg, Joeri Opdam are thanked for SEM analysis, assisting with freeze-drying, and for drawing the schematic representation of the colloidal tubes, respectively.

Publisher Copyright:
© The Royal Society of Chemistry 2020.

Funding

Y. Guo is supported by Chinese Scholarship council (File No. 201306200056). Kanvaly Lacina, Hans Meeldijk and Chris Schneijdenberg, Joeri Opdam are thanked for SEM analysis, assisting with freeze-drying, and for drawing the schematic representation of the colloidal tubes, respectively.

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