TY - JOUR
T1 - Reply to comment on "Probing the equilibrium dynamics of colloidal hard spheres above the mode-coupling glass transition
AU - Brambilla, G.
AU - al Masri, J.H.M.
AU - Pierno, M.
AU - Berthier, L.
AU - Cipelletti, L.
PY - 2010
Y1 - 2010
N2 - [1] (RWF) use
mode-coupling theory (MCT) to analyze a subset of our
data [2] and question our claim that dense colloidal hard
spheres enter at large volume fraction ’, a dynamical
regime not described by MCT. To reach this conclusion,
RWF fit intermediate scattering functions (ISFs) obtained
by light scattering to the outcome of MCT calculations for
a monodisperse system of hard spheres. By freely adjusting
the short-time diffusion coefficient Ds, and w, the parameter
fixing the relative contribution of self and collective
dynamics to the signal, they reproduce well the short-time
decay of the data to a plateau. More crucially, to reproduce
also the long-time decay, RWF need to adjust, for each
experimental volume fraction ’ considered, the volume
fraction ’mct of the corresponding theoretical curve. Since
the shape of the ISF does not change much with ’, this
analysis is nearly equivalent to adjusting the typical relaxation
time
ð’Þ, which we had done more simply by
fitting the data to a stretched exponential form [2].
AB - [1] (RWF) use
mode-coupling theory (MCT) to analyze a subset of our
data [2] and question our claim that dense colloidal hard
spheres enter at large volume fraction ’, a dynamical
regime not described by MCT. To reach this conclusion,
RWF fit intermediate scattering functions (ISFs) obtained
by light scattering to the outcome of MCT calculations for
a monodisperse system of hard spheres. By freely adjusting
the short-time diffusion coefficient Ds, and w, the parameter
fixing the relative contribution of self and collective
dynamics to the signal, they reproduce well the short-time
decay of the data to a plateau. More crucially, to reproduce
also the long-time decay, RWF need to adjust, for each
experimental volume fraction ’ considered, the volume
fraction ’mct of the corresponding theoretical curve. Since
the shape of the ISF does not change much with ’, this
analysis is nearly equivalent to adjusting the typical relaxation
time
ð’Þ, which we had done more simply by
fitting the data to a stretched exponential form [2].
U2 - 10.1103/PhysRevLett.105.199605
DO - 10.1103/PhysRevLett.105.199605
M3 - Comment/Letter to the editor
SN - 0031-9007
VL - 105
JO - Physical Review Letters
JF - Physical Review Letters
M1 - 199605
ER -