Removing grain boundaries from three-dimensional colloidal crystals using active dopants

B. van der Meer, M. Dijkstra, L.C. Filion

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Using computer simulations we explore how grain boundaries can be removed from three-dimensional colloidal crystals by doping with a small fraction of active colloids. We show that for sufficient selfpropulsion, the system is driven into a crystal-fluid coexistence. In this phase separated regime, the active dopants become mobile and spontaneously gather at the grain boundaries. The resulting surface melting and recrystallization of domains result in the motion of the grain boundaries over time and lead to the formation of a large single crystal. However, when the self-propulsion is too low to cause a phase separation, we observe no significant enhancement of grain growth.
Original languageEnglish
Pages (from-to)5630-5635
Number of pages6
JournalSoft Matter
Volume12
DOIs
Publication statusPublished - 30 May 2016

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