Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement

V. Lyaskovskyy; N. Elders; A.W. Ehlers; M. Lutz; J.C. Slootweg; K. Lammertsma

doi:10.1021/ja203083c

Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement

V. Lyaskovskyy, N. Elders, A.W. Ehlers, M. Lutz, J.C. Slootweg, K. Lammertsma

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

Original language	English
Pages (from-to)	9704-9707
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	25
DOIs	https://doi.org/10.1021/ja203083c
Publication status	Published - 2011

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title = "Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement",

abstract = "In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit{\textquoteright}s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.",

author = "V. Lyaskovskyy and N. Elders and A.W. Ehlers and M. Lutz and J.C. Slootweg and K. Lammertsma",

year = "2011",

doi = "10.1021/ja203083c",

language = "English",

volume = "133",

pages = "9704--9707",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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T1 - Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement

AU - Lyaskovskyy, V.

AU - Elders, N.

AU - Ehlers, A.W.

AU - Lutz, M.

AU - Slootweg, J.C.

AU - Lammertsma, K.

PY - 2011

Y1 - 2011

N2 - In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

AB - In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

U2 - 10.1021/ja203083c

DO - 10.1021/ja203083c

M3 - Article

SN - 0002-7863

VL - 133

SP - 9704

EP - 9707

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 25

ER -

Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene–cyclobutadiene rearrangement

Abstract

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