TY - JOUR
T1 - Re(I) complexes of pyridyl-phosphinines and 2,2’-bipyridine derivatives: A comparison study
AU - Loibl, Antonia
AU - Weber, Manuela
AU - Lutz, Martin
AU - Müller, Christian
PY - 2019/3/31
Y1 - 2019/3/31
N2 - The coordination chemistry of 2‐(2′‐pyridyl)‐4,6‐diarylphosphinines towards ReI has been investigated and compared to the structurally analogous 2,2′‐bipyridine derivatives. The different steric properties of the chelating pyridylphosphinines with respect to substituted bipyridines lead to considerable differences in the structures of the mononuclear [(P^N)Re(CO)3X] and [(N^N)Re(CO)3X] (X = Cl, Br) complexes, both in the solid state and in solution. The phosphinine‐based coordination compounds are highly sensitive towards nucleophilic attack and react reversibly with water at the P=C double bond.
AB - The coordination chemistry of 2‐(2′‐pyridyl)‐4,6‐diarylphosphinines towards ReI has been investigated and compared to the structurally analogous 2,2′‐bipyridine derivatives. The different steric properties of the chelating pyridylphosphinines with respect to substituted bipyridines lead to considerable differences in the structures of the mononuclear [(P^N)Re(CO)3X] and [(N^N)Re(CO)3X] (X = Cl, Br) complexes, both in the solid state and in solution. The phosphinine‐based coordination compounds are highly sensitive towards nucleophilic attack and react reversibly with water at the P=C double bond.
U2 - 10.1002/ejic.201801234
DO - 10.1002/ejic.201801234
M3 - Article
SN - 1434-1948
VL - 2019
SP - 1575
EP - 1585
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 11-12
ER -