Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

Y. Gloaguen; W. Jacobs; B. de Bruin; M. Lutz; J.I. van der Vlugt

doi:10.1021/ic302301h

Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

Y. Gloaguen, W. Jacobs, B. de Bruin, M. Lutz, J.I. van der Vlugt

Sub Crystal and Structural Chemistry

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The first example of an iridium(I) species bearing a terminal phosphido (PR2 −) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium- (I)−gold(I) dinuclear species.

Original language	English
Pages (from-to)	1682-1684
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	4
DOIs	https://doi.org/10.1021/ic302301h
Publication status	Published - 2013

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title = "Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand",

abstract = "The first example of an iridium(I) species bearing a terminal phosphido (PR2 −) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium- (I)−gold(I) dinuclear species.",

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AU - Jacobs, W.

AU - de Bruin, B.

AU - Lutz, M.

AU - van der Vlugt, J.I.

PY - 2013

Y1 - 2013

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AB - The first example of an iridium(I) species bearing a terminal phosphido (PR2 −) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium- (I)−gold(I) dinuclear species.

U2 - 10.1021/ic302301h

DO - 10.1021/ic302301h

M3 - Article

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SP - 1682

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

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Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

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