Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes

Lars Killian; Roel L.M. Bienenmann; Daniël L.J. Broere

doi:10.1021/acs.organomet.2c00458

Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes

Lars Killian
, Roel L.M. Bienenmann
, Daniël L.J. Broere^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Steric properties of ligands are an important parameter for tuning the reactivity of the corresponding complexes. For various ligands used in mononuclear complexes, methods have been developed to quantify their steric bulk. In this work, we present an expansion of the buried volume and the G-parameter to quantify the steric properties of 1,8-napthyridine-based dinuclear complexes. Using this methodology, we explored the tunability of the steric properties associated with these ligands and complexes.

Original language	English
Pages (from-to)	27-37
Number of pages	11
Journal	Organometallics
Volume	42
Issue number	1
DOIs	https://doi.org/10.1021/acs.organomet.2c00458
Publication status	Published - 9 Jan 2023

Bibliographical note

Publisher Copyright:
© 2022 The Authors. Published by American Chemical Society.

Funding

The work in this paper was supported by The Netherlands Organization of Scientific Research (VI.Veni.192.074 to D.L.J.B.). This work made use of the Dutch national e-infrastructure with the support of the SURF Cooperative using grants no. EINF-1254 and EINF-3520. A preprint of this manuscript was previously published under doi: 10.26434/chemrxiv-2022-1 pp03. We gratefully acknowledge Dr. Emily Monkcom for designing the cover art for this paper.

Funders	Funder number
SURF	EINF-3520, EINF-1254
Nederlandse Organisatie voor Wetenschappelijk Onderzoek	VI.Veni.192.074

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Quantification of the Steric Properties of 1,8-Naphthyridine-Based Ligands in Dinuclear Complexes

Abstract

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