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Preparation and performance of a silica-supported V2O5 on TiO2 catalyst for the selective reduction of NO with NH3

  • E. T C Vogt*
  • , A. Boot
  • , A. J. van Dillen
  • , J. W. Geus
  • , F. J J G Janssen
  • , F. M G van den Kerkhof
  • *Corresponding author for this work
    • Arnhem Institutions of the Dutch Electricity Utilities
    • External unknown
    • KEMA Netherlands Ltd
    • Utrecht University

    Research output: Contribution to journalArticleAcademicpeer-review

    Abstract

    A preparation technique is described in which a layer of TiO2 completely covering the support can be deposited onto silica. Onto the support thus modified, V2O5 can be applied to result in a catalyst suitable for the selective catalytic reduction (SCR) of NOx with NH3. To obtain the required selectivity in the reduction of NOx the silica surface must be completely covered with TiO2. Catalysts prepared according to the above procedure exhibit good activity and a completely selective reduction of NO to N2 at temperatures to 350 °C. At higher temperatures selective oxidation of the NH3 to N2 is observed.

    Original languageEnglish
    Pages (from-to)313-320
    Number of pages8
    JournalJournal of Catalysis
    Volume114
    Issue number2
    Publication statusPublished - 1 Dec 1988

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