Preorganized Frustrated Lewis Pairs

F. Bertini; V. Lyaskovskyy; B.J.J. Timmer; F.J.J. de Kanter; M. Lutz; A.W. Ehlers; J.C. Slootweg; K. Lammertsma

doi:10.1021/ja210214r

Preorganized Frustrated Lewis Pairs

F. Bertini, V. Lyaskovskyy, B.J.J. Timmer, F.J.J. de Kanter, M. Lutz, A.W. Ehlers, J.C. Slootweg, K. Lammertsma

Sub Crystal and Structural Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
DOIs	https://doi.org/10.1021/ja210214r
Publication status	Published - 2012

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title = "Preorganized Frustrated Lewis Pairs",

abstract = "Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.",

author = "F. Bertini and V. Lyaskovskyy and B.J.J. Timmer and {de Kanter}, F.J.J. and M. Lutz and A.W. Ehlers and J.C. Slootweg and K. Lammertsma",

year = "2012",

doi = "10.1021/ja210214r",

language = "English",

volume = "134",

pages = "201--204",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - Preorganized Frustrated Lewis Pairs

AU - Bertini, F.

AU - Lyaskovskyy, V.

AU - Timmer, B.J.J.

AU - de Kanter, F.J.J.

AU - Lutz, M.

AU - Ehlers, A.W.

AU - Slootweg, J.C.

AU - Lammertsma, K.

PY - 2012

Y1 - 2012

N2 - Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.

AB - Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.

U2 - 10.1021/ja210214r

DO - 10.1021/ja210214r

M3 - Article

SN - 0002-7863

VL - 134

SP - 201

EP - 204

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Preorganized Frustrated Lewis Pairs

Abstract

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