TY - JOUR
T1 - Phosphinidene addition to conjugated allenes
AU - Bertini, F.
AU - Wit, J.B.M.
AU - Ünal, M.
AU - de Kanter, F.J.J.
AU - Schakel, M.
AU - Slootweg, J.C.
AU - Ehlers, A.W.
AU - Nijbacker, T.
AU - Komen, C.M.D.
AU - Lutz, M.
AU - Spek, A.L.
AU - Lammertsma, K.
PY - 2009
Y1 - 2009
N2 - Generating the transient electrophilic tungsten pentacarbonyl-phenylphosphinidene complex PhPW(CO)5 in the presence of 2,7-dimethylocta-2,3,5,6-tetraene leads to the formation of a 3,4-disubstituted phosphole or a complexed phospholene, depending on the reaction conditions. The formation of the phospholene results from the reaction of PhPW(CO)5 with the diallene, while the formation of the phosphole arises from reaction with 3,4-diisopropylidene-cyclobutene, which is formed in situ from the isomerization of the conjugated allene.
AB - Generating the transient electrophilic tungsten pentacarbonyl-phenylphosphinidene complex PhPW(CO)5 in the presence of 2,7-dimethylocta-2,3,5,6-tetraene leads to the formation of a 3,4-disubstituted phosphole or a complexed phospholene, depending on the reaction conditions. The formation of the phospholene results from the reaction of PhPW(CO)5 with the diallene, while the formation of the phosphole arises from reaction with 3,4-diisopropylidene-cyclobutene, which is formed in situ from the isomerization of the conjugated allene.
M3 - Article
SN - 1615-4150
VL - 351
SP - 1132
EP - 1138
JO - Advanced synthesis & catalysis
JF - Advanced synthesis & catalysis
IS - 7-8
ER -