P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines

J. Li; A.J. Minnaard; R.J.M. Klein Gebbink; G. van Koten

P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines

J. Li
, A.J. Minnaard
, R.J.M. Klein Gebbink
, G. van Koten

Dept of Chemistry

extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The P0CP0-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.

Original language	Undefined/Unknown
Pages (from-to)	2232-2235
Number of pages	4
Journal	Tetrahedron Letters
Volume	50
Publication status	Published - 2009

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Cite this

@article{96964dd7e468440cb2062d95f2c4aa39,

title = "P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines",

abstract = "The P0CP0-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.",

author = "J. Li and A.J. Minnaard and \{Klein Gebbink\}, R.J.M. and \{van Koten\}, G.",

year = "2009",

language = "Undefined/Unknown",

volume = "50",

pages = "2232--2235",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

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TY - JOUR

T1 - P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines

AU - Li, J.

AU - Minnaard, A.J.

AU - Klein Gebbink, R.J.M.

AU - van Koten, G.

PY - 2009

Y1 - 2009

N2 - The P0CP0-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.

AB - The P0CP0-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.

M3 - Article

SN - 0040-4039

VL - 50

SP - 2232

EP - 2235

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -