Particle shape effects in colloidal crystals and colloidal liquid crystals: Small-angle X-ray scattering studies with microradian resolution

Andrei V. Petukhov*, Janne-Mieke Meijer, Gert Jan Vroege

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

Abstract

Small-angle X-ray scattering (SAXS) is an indispensable tool in structural investigations of self-assembled colloidal crystals and colloidal liquid crystals. This paper reviews recent studies of the particle shape effects on the crystal structure as revealed by SAXS. Rod-like, plate-like, biaxial board-like as well as cubic-like shapes are discussed. Since relatively large, (sub)micron particles are often used in these studies, we describe the principles of the microradian X-ray diffraction technique that allows detailed characterisation of the periodic order including the determination of the intrinsic width of the Bragg peaks. (C) 2015 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)272-281
Number of pages10
JournalCurrent opinion in colloid & interface science
Volume20
Issue number4
DOIs
Publication statusPublished - Aug 2015

Keywords

  • Colloidal crystal
  • Colloidal liquid crystal
  • Small-angle X-ray
  • Scattering
  • Microradian resolution
  • Anisotropic colloids
  • AQUEOUS SUSPENSIONS
  • PHASE-BEHAVIOR
  • GOETHITE NANORODS
  • COMPLEX STRUCTURES
  • MAGNETIC-FIELD
  • DIFFRACTION
  • TRANSITIONS
  • PLATELETS
  • SUPERLATTICES
  • DISPERSIONS

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