Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase

Robertus J. M. Klein Gebbink; Masayuki Watanabe; Russell C. Pratt; T. Daniel P. Stack

Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase

Robertus J. M. Klein Gebbink, Masayuki Watanabe, Russell C. Pratt, T. Daniel P. Stack

Sub Organic Chemistry and Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Cupric complexes of a novel phenanthroline-phenolate ligand have strongly distorted coordination geometries and electrochemical properties conducive to modeling the spectroscopy and reactivity of the enzyme galactose oxidase.

Original language	English
Pages (from-to)	630-631
Number of pages	2
Journal	Chemical Communications
Issue number	5
Publication status	Published - 7 Mar 2003

Keywords

copper complex
galactose oxidase
ligand
phenanthroline derivative
phenol derivative
article
chemical reaction
crystal structure
model
oxidation
spectroscopy
synthesis
X ray crystallography

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@article{b12d85aa3040486b98aac6b79d96b247,

title = "Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase",

abstract = "Cupric complexes of a novel phenanthroline-phenolate ligand have strongly distorted coordination geometries and electrochemical properties conducive to modeling the spectroscopy and reactivity of the enzyme galactose oxidase.",

keywords = "copper complex, galactose oxidase, ligand, phenanthroline derivative, phenol derivative, article, chemical reaction, crystal structure, model, oxidation, spectroscopy, synthesis, X ray crystallography",

author = "{Klein Gebbink}, {Robertus J. M.} and Masayuki Watanabe and Pratt, {Russell C.} and Stack, {T. Daniel P.}",

year = "2003",

month = mar,

day = "7",

language = "English",

pages = "630--631",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase

AU - Klein Gebbink, Robertus J. M.

AU - Watanabe, Masayuki

AU - Pratt, Russell C.

AU - Stack, T. Daniel P.

PY - 2003/3/7

Y1 - 2003/3/7

N2 - Cupric complexes of a novel phenanthroline-phenolate ligand have strongly distorted coordination geometries and electrochemical properties conducive to modeling the spectroscopy and reactivity of the enzyme galactose oxidase.

AB - Cupric complexes of a novel phenanthroline-phenolate ligand have strongly distorted coordination geometries and electrochemical properties conducive to modeling the spectroscopy and reactivity of the enzyme galactose oxidase.

KW - copper complex

KW - galactose oxidase

KW - ligand

KW - phenanthroline derivative

KW - phenol derivative

KW - article

KW - chemical reaction

KW - crystal structure

KW - model

KW - oxidation

KW - spectroscopy

KW - synthesis

KW - X ray crystallography

M3 - Article

SN - 1359-7345

SP - 630

EP - 631

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase

Abstract

Keywords

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