Order-Disorder in Diaquobis(salicylato)copper(II) Revisited

Martin Lutz; Louise Kroon - Batenburg

doi:10.5562/cca3362

Order-Disorder in Diaquobis(salicylato)copper(II) Revisited

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks.
From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers.
The layer stacking is disordered and from simulation

Original language	English
Pages (from-to)	289-298
Journal	Croatica Chemica Acta
Volume	91
Issue number	2
DOIs	https://doi.org/10.5562/cca3362
Publication status	Published - 28 Jun 2018

Keywords

diffuse scattering
OD structure
hydrogen-bonded layers
copper complex

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title = "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited",

abstract = "We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks.From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers.The layer stacking is disordered and from simulation",

keywords = "diffuse scattering, OD structure, hydrogen-bonded layers, copper complex",

author = "Martin Lutz and {Kroon - Batenburg}, Louise",

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AU - Kroon - Batenburg, Louise

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N2 - We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks.From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers.The layer stacking is disordered and from simulation

AB - We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks.From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers.The layer stacking is disordered and from simulation

KW - diffuse scattering

KW - OD structure

KW - hydrogen-bonded layers

KW - copper complex

U2 - 10.5562/cca3362

DO - 10.5562/cca3362

M3 - Article

SN - 0011-1643

VL - 91

SP - 289

EP - 298

JO - Croatica Chemica Acta

JF - Croatica Chemica Acta

IS - 2

ER -

Order-Disorder in Diaquobis(salicylato)copper(II) Revisited

Abstract

Keywords

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