On the Equivalence of von Neumann and Thermodynamic Entropy

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Abstract

In 1932, John von Neumann argued for the equivalence of the thermodynamic entropy and −Trρlnρ, since known as the von Neumann entropy. Meir Hemmo and Orly R. Shenker recently challenged this argument by pointing out an alleged discrepancy between the two entropies in the single-particle case, concluding that they must be distinct. In this article, their argument is shown to be problematic as it (a) allows for a violation of the second law of thermodynamics and (b) is based on an incorrect calculation of the von Neumann entropy.
Original languageEnglish
JournalPhilosophy of Science
Volume87
Issue number2
DOIs
Publication statusPublished - Apr 2020
Externally publishedYes

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