Novel heteroditopic chelate for self-assembled gadolinium(II) complex with high relaxitivity

R. Ruloff; G. van Koten; A.E. Merbach

doi:10.1039/B400169A

Novel heteroditopic chelate for self-assembled gadolinium(II) complex with high relaxitivity

R. Ruloff, G. van Koten, A.E. Merbach

extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

[Fe(tpy-DTTA)2Gd2] is a self-assembled trinuclear complex based on a novel ligand in which a terpyridine and a poly(amino carboxylate) moiety are connected; it has a well-defined topology with favourable features to attain high relaxivities, i.e. a rigid FeII(tpy)2 core, reduced flexibility at the periphery thanks to a short linker, and efficient separation of the two GdIII centres.

Original language	English
Pages (from-to)	842-843
Number of pages	2
Journal	Chemical Communications
Volume	2004
Issue number	7
DOIs	https://doi.org/10.1039/B400169A
Publication status	Published - 2004

Access to Document

10.1039/B400169A

Cite this

@article{c51db5b4a8fa46438365226456260d58,

title = "Novel heteroditopic chelate for self-assembled gadolinium(II) complex with high relaxitivity",

abstract = "[Fe(tpy-DTTA)2Gd2] is a self-assembled trinuclear complex based on a novel ligand in which a terpyridine and a poly(amino carboxylate) moiety are connected; it has a well-defined topology with favourable features to attain high relaxivities, i.e. a rigid FeII(tpy)2 core, reduced flexibility at the periphery thanks to a short linker, and efficient separation of the two GdIII centres.",

author = "R. Ruloff and {van Koten}, G. and A.E. Merbach",

year = "2004",

doi = "10.1039/B400169A",

language = "English",

volume = "2004",

pages = "842--843",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Novel heteroditopic chelate for self-assembled gadolinium(II) complex with high relaxitivity

AU - Ruloff, R.

AU - van Koten, G.

AU - Merbach, A.E.

PY - 2004

Y1 - 2004

N2 - [Fe(tpy-DTTA)2Gd2] is a self-assembled trinuclear complex based on a novel ligand in which a terpyridine and a poly(amino carboxylate) moiety are connected; it has a well-defined topology with favourable features to attain high relaxivities, i.e. a rigid FeII(tpy)2 core, reduced flexibility at the periphery thanks to a short linker, and efficient separation of the two GdIII centres.

AB - [Fe(tpy-DTTA)2Gd2] is a self-assembled trinuclear complex based on a novel ligand in which a terpyridine and a poly(amino carboxylate) moiety are connected; it has a well-defined topology with favourable features to attain high relaxivities, i.e. a rigid FeII(tpy)2 core, reduced flexibility at the periphery thanks to a short linker, and efficient separation of the two GdIII centres.

U2 - 10.1039/B400169A

DO - 10.1039/B400169A

M3 - Article

SN - 1359-7345

VL - 2004

SP - 842

EP - 843

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Novel heteroditopic chelate for self-assembled gadolinium(II) complex with high relaxitivity

Abstract

Access to Document

Fingerprint

Cite this