Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters

Robbert Van Putten; Evgeny A. Uslamin; Marcel Garbe; Chong Liu; Angela Gonzalez-de-castro; Martin Lutz; Kathrin Junge; Emiel J. M. Hensen; Matthias Beller; Laurent Lefort; Evgeny A. Pidko

doi:10.1002/anie.201701365

Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters

Robbert Van Putten, Evgeny A. Uslamin, Marcel Garbe, Chong Liu, Angela Gonzalez-de-castro, Martin Lutz, Kathrin Junge, Emiel J. M. Hensen, Matthias Beller, Laurent Lefort, Evgeny A. Pidko

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Catalytic hydrogenation of carboxylic acid esters isessential for the green production of pharmaceuticals,fragran-ces,and fine chemicals.Herein, we report the efficient hydro-genation of esters with manganese catalysts based on simplebidentate aminophosphine ligands.Monoligated Mn PNcomplexes are particularly active for the conversion of estersinto the corresponding alcohols at Mn concentrations as low as0.2 mol%inthe presence of sub-stoichiometric amounts ofKOtBu base.

Original language	English
Pages (from-to)	7531-7534
Number of pages	4
Journal	Angewandte Chemie-International Edition
Volume	56
Issue number	26
DOIs	https://doi.org/10.1002/anie.201701365
Publication status	Published - 19 Jun 2017

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title = "Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters",

abstract = "Catalytic hydrogenation of carboxylic acid esters isessential for the green production of pharmaceuticals,fragran-ces,and fine chemicals.Herein, we report the efficient hydro-genation of esters with manganese catalysts based on simplebidentate aminophosphine ligands.Monoligated Mn PNcomplexes are particularly active for the conversion of estersinto the corresponding alcohols at Mn concentrations as low as0.2 mol%inthe presence of sub-stoichiometric amounts ofKOtBu base.",

author = "Robbert Van Putten and Uslamin, {Evgeny A.} and Marcel Garbe and Chong Liu and Angela Gonzalez-de-castro and Martin Lutz and Kathrin Junge and Hensen, {Emiel J. M.} and Matthias Beller and Laurent Lefort and Pidko, {Evgeny A.}",

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month = jun,

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doi = "10.1002/anie.201701365",

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T1 - Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters

AU - Van Putten, Robbert

AU - Uslamin, Evgeny A.

AU - Garbe, Marcel

AU - Liu, Chong

AU - Gonzalez-de-castro, Angela

AU - Lutz, Martin

AU - Junge, Kathrin

AU - Hensen, Emiel J. M.

AU - Beller, Matthias

AU - Lefort, Laurent

AU - Pidko, Evgeny A.

PY - 2017/6/19

Y1 - 2017/6/19

N2 - Catalytic hydrogenation of carboxylic acid esters isessential for the green production of pharmaceuticals,fragran-ces,and fine chemicals.Herein, we report the efficient hydro-genation of esters with manganese catalysts based on simplebidentate aminophosphine ligands.Monoligated Mn PNcomplexes are particularly active for the conversion of estersinto the corresponding alcohols at Mn concentrations as low as0.2 mol%inthe presence of sub-stoichiometric amounts ofKOtBu base.

AB - Catalytic hydrogenation of carboxylic acid esters isessential for the green production of pharmaceuticals,fragran-ces,and fine chemicals.Herein, we report the efficient hydro-genation of esters with manganese catalysts based on simplebidentate aminophosphine ligands.Monoligated Mn PNcomplexes are particularly active for the conversion of estersinto the corresponding alcohols at Mn concentrations as low as0.2 mol%inthe presence of sub-stoichiometric amounts ofKOtBu base.

U2 - 10.1002/anie.201701365

DO - 10.1002/anie.201701365

M3 - Article

SN - 1433-7851

VL - 56

SP - 7531

EP - 7534

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

IS - 26

ER -

Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters

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