New 'bucky-ligands'. Potentially monoanionic terdentate diamino aryl pincer ligands anchored to C60

Michel D. Meijer, Mathias Rump, Robert A. Gossage, Johann H.T.B. Jastrzebski, Gerard Van Koten

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Two new methanofullerenes have been prepared by the reaction of C60with diazo substituted, potentially monoanionic, terdentate diamino aryl ligands, yielding a mixture of the open valence [5,6]- and closed valence [6,6]-isomers. Single isomers of the pure [6,6]-methanofullerenes were obtained by heating these mixtures in toluene solution.
Original languageEnglish
Pages (from-to)6773-6776
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number37
Publication statusPublished - 10 Sept 1998

Keywords

  • fullerene
  • article
  • ligand binding
  • metal binding
  • reaction analysis
  • structure analysis
  • synthesis

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