Metal-Directed Self-Assembly of a ZnII-salpyr Complex into a Supramolecular Vase Structure

A.W. Kleij; M. Kuil; D.M. Tooke; A.L. Spek; J.N.H. Reek

Metal-Directed Self-Assembly of a ZnII-salpyr Complex into a Supramolecular Vase Structure

A.W. Kleij, M. Kuil, D.M. Tooke, A.L. Spek, J.N.H. Reek

Dept of Chemistry

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Research output: Contribution to journal › Article › Academic › peer-review

Abstract

A new type of supramolecular building block, ZnII-salpyr [salpyr = N,N'-3-pyridylenebis(salicylideneimine)], is described that contains both a pyridyl donor and a Lewis acidic ZnII acceptor site in the salen framework. As a consequence, this building block self-organizes into a stable tetrameric vase structure via cooperative intermolecular Zn-Npyr interactions.

Original language	Undefined/Unknown
Pages (from-to)	5829-5831
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	15
Publication status	Published - 2007

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Cite this

@article{cb4ff9a118294e60ac0a0e717ef53765,

title = "Metal-Directed Self-Assembly of a ZnII-salpyr Complex into a Supramolecular Vase Structure",

abstract = "A new type of supramolecular building block, ZnII-salpyr [salpyr = N,N'-3-pyridylenebis(salicylideneimine)], is described that contains both a pyridyl donor and a Lewis acidic ZnII acceptor site in the salen framework. As a consequence, this building block self-organizes into a stable tetrameric vase structure via cooperative intermolecular Zn-Npyr interactions.",

author = "A.W. Kleij and M. Kuil and D.M. Tooke and A.L. Spek and J.N.H. Reek",

year = "2007",

language = "Undefined/Unknown",

volume = "46",

pages = "5829--5831",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "15",

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TY - JOUR

T1 - Metal-Directed Self-Assembly of a ZnII-salpyr Complex into a Supramolecular Vase Structure

AU - Kleij, A.W.

AU - Kuil, M.

AU - Tooke, D.M.

AU - Spek, A.L.

AU - Reek, J.N.H.

PY - 2007

Y1 - 2007

N2 - A new type of supramolecular building block, ZnII-salpyr [salpyr = N,N'-3-pyridylenebis(salicylideneimine)], is described that contains both a pyridyl donor and a Lewis acidic ZnII acceptor site in the salen framework. As a consequence, this building block self-organizes into a stable tetrameric vase structure via cooperative intermolecular Zn-Npyr interactions.

AB - A new type of supramolecular building block, ZnII-salpyr [salpyr = N,N'-3-pyridylenebis(salicylideneimine)], is described that contains both a pyridyl donor and a Lewis acidic ZnII acceptor site in the salen framework. As a consequence, this building block self-organizes into a stable tetrameric vase structure via cooperative intermolecular Zn-Npyr interactions.

M3 - Article

SN - 0020-1669

VL - 46

SP - 5829

EP - 5831

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -