Mass spectrometry of the intramolecular nitrogen isotope distribution of environmental nitrous oxide using fragment-ion analysis

C. A.M. Brenninkmeijer; T. Röckmann

doi:10.1002/(SICI)1097-0231(19991030)13:20<2028::AID-RCM751>3.0.CO;2-J

Mass spectrometry of the intramolecular nitrogen isotope distribution of environmental nitrous oxide using fragment-ion analysis

C. A.M. Brenninkmeijer^*
, T. Röckmann

^*Corresponding author for this work

Max Planck Institute for Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Mass spectrometry is applied to measure the intramolecular distribution of ¹⁵N in N₂O samples of near natural isotopic composition. The method is relatively straightforward and based on the analysis of the ¹⁴NO and ¹⁵NO fragment ion beams at mass 30 and 31, respectively, in combination with the standard analysis of the masses 44, 45, and 46 of the non-fragmented N₂O. Various complications in the application, not all of which are resolved at present, are discussed.

Original language	English
Pages (from-to)	2028-2033
Number of pages	6
Journal	Rapid Communications in Mass Spectrometry
Volume	13
Issue number	20
DOIs	https://doi.org/10.1002/(SICI)1097-0231(19991030)13:20<2028::AID-RCM751>3.0.CO;2-J
Publication status	Published - 1 Jan 1999

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10.1002/(SICI)1097-0231(19991030)13:20<2028::AID-RCM751>3.0.CO;2-J

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abstract = "Mass spectrometry is applied to measure the intramolecular distribution of 15N in N2O samples of near natural isotopic composition. The method is relatively straightforward and based on the analysis of the 14NO and 15NO fragment ion beams at mass 30 and 31, respectively, in combination with the standard analysis of the masses 44, 45, and 46 of the non-fragmented N2O. Various complications in the application, not all of which are resolved at present, are discussed.",

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AU - Röckmann, T.

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N2 - Mass spectrometry is applied to measure the intramolecular distribution of 15N in N2O samples of near natural isotopic composition. The method is relatively straightforward and based on the analysis of the 14NO and 15NO fragment ion beams at mass 30 and 31, respectively, in combination with the standard analysis of the masses 44, 45, and 46 of the non-fragmented N2O. Various complications in the application, not all of which are resolved at present, are discussed.

AB - Mass spectrometry is applied to measure the intramolecular distribution of 15N in N2O samples of near natural isotopic composition. The method is relatively straightforward and based on the analysis of the 14NO and 15NO fragment ion beams at mass 30 and 31, respectively, in combination with the standard analysis of the masses 44, 45, and 46 of the non-fragmented N2O. Various complications in the application, not all of which are resolved at present, are discussed.

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DO - 10.1002/(SICI)1097-0231(19991030)13:20<2028::AID-RCM751>3.0.CO;2-J

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JF - Rapid Communications in Mass Spectrometry

IS - 20

ER -

Mass spectrometry of the intramolecular nitrogen isotope distribution of environmental nitrous oxide using fragment-ion analysis

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