Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars

Daan Noort; Gerrit H. Veeneman; Geert Jan P.H. Boons; Gijs A. Van Der Marel; Gerard J. Mulder; Jacques H. Van Boom

doi:10.1055/s-1990-21034

Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars

Daan Noort
, Gerrit H. Veeneman
, Geert Jan P.H. Boons
, Gijs A. Van Der Marel
, Gerard J. Mulder
, Jacques H. Van Boom^*

^*Corresponding author for this work

Leiden University
extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.

Original language	English
Pages (from-to)	205-206
Number of pages	2
Journal	Synlett
Volume	1990
Issue number	4
DOIs	https://doi.org/10.1055/s-1990-21034
Publication status	Published - 1 Apr 1990
Externally published	Yes

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title = "Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars",

abstract = "Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.",

author = "Daan Noort and Veeneman, \{Gerrit H.\} and Boons, \{Geert Jan P.H.\} and \{Van Der Marel\}, \{Gijs A.\} and Mulder, \{Gerard J.\} and \{Van Boom\}, \{Jacques H.\}",

year = "1990",

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doi = "10.1055/s-1990-21034",

language = "English",

volume = "1990",

pages = "205--206",

journal = "Synlett",

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T1 - Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars

AU - Noort, Daan

AU - Veeneman, Gerrit H.

AU - Boons, Geert Jan P.H.

AU - Van Der Marel, Gijs A.

AU - Mulder, Gerard J.

AU - Van Boom, Jacques H.

PY - 1990/4/1

Y1 - 1990/4/1

N2 - Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.

AB - Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.

UR - https://www.scopus.com/pages/publications/84987569497

U2 - 10.1055/s-1990-21034

DO - 10.1055/s-1990-21034

M3 - Article

AN - SCOPUS:84987569497

SN - 0936-5214

VL - 1990

SP - 205

EP - 206

JO - Synlett

JF - Synlett

IS - 4

ER -

Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars

Abstract

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