Iodonium ion promoted reactions at the anomeric C-2 center of 1-methylene sugars

Daan Noort, Gerrit H. Veeneman, Geert Jan P.H. Boons, Gijs A. Van Der Marel, Gerard J. Mulder, Jacques H. Van Boom*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.

Original languageEnglish
Pages (from-to)205-206
Number of pages2
JournalSynlett
Volume1990
Issue number4
DOIs
Publication statusPublished - 1 Apr 1990
Externally publishedYes

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