Skip to main navigation Skip to search Skip to main content

Introduction to depletion interaction and colloidal phase behaviour

  • Remco Tuinier*
  • *Corresponding author for this work
  • Eindhoven University of Technology

Research output: Chapter in Book/Report/Conference proceedingChapterAcademicpeer-review

Abstract

Efforts to explain physical properties of colloidal suspensions in terms of the forces that act between the colloidal particles go back to the beginning of the 20th century. In the second half of the last century theoretical progress clarified that the stability of colloidal particles is also affected by non-adsorbing polymers in solution, as first explained by Asakura and Oosawa in Japan using the excluded and free volume concepts. Here an introduction to the depletion interaction and resulting phase behaviour in colloidal suspensions is provided. The theory for the phase behaviour of colloidal dispersions is developed here starting from the Van der Waals theory for the as-liquid phase transition. Subsequently, the hard sphere fluid-solid phase transition is explained. Next, an attractive Yukawa hard-core model is used to outline the effects of varying the range of attraction on the phase behaviour of a colloidal suspension of attractive particles. Finally, the phase states that can be found in a colloidal hard sphere dispersion plus depletants are explained.

Original languageEnglish
Title of host publicationLecture Notes in Physics
PublisherSpringer
Pages71-106
Number of pages36
Volume917
DOIs
Publication statusPublished - 1 Oct 2016

Publication series

NameLecture Notes in Physics
Volume917
ISSN (Print)00758450

Fingerprint

Dive into the research topics of 'Introduction to depletion interaction and colloidal phase behaviour'. Together they form a unique fingerprint.

Cite this