TY - JOUR
T1 - Interaction of arylmetal compounds of group 1B with copper(I) and silver(I) trifluoromethanesulphonate; a novel biaryl synthesis and a route to hexanuclear aryl-CuAg, -AgAu, and -CuAu clusters
AU - Van Koten, Gerard
AU - Jastrzebski, Johann T B H
AU - Noltes, Jan G.
PY - 1977
Y1 - 1977
N2 - Whereas selective biaryl formation is observed when arylcopper compounds 4-MeC6H4Cu, 2-Me2NC6H4Cu, and 2-Me2NCH2C6H4Cu are treated in exact 1:1 molar ratio with (CF3SO3)Cu, reactions of 2-Me2NC6H4M (M = Cu or Au) with (CF 3SO3)Cu (2:1) and of Ar4Au2Li 2 with (CF3SO3)Cu or (CF3SO 3)Ag (1:2) afford novel hexanuclear cluster compounds of the type Ar4M4M′2(CF3SO 3)2.
AB - Whereas selective biaryl formation is observed when arylcopper compounds 4-MeC6H4Cu, 2-Me2NC6H4Cu, and 2-Me2NCH2C6H4Cu are treated in exact 1:1 molar ratio with (CF3SO3)Cu, reactions of 2-Me2NC6H4M (M = Cu or Au) with (CF 3SO3)Cu (2:1) and of Ar4Au2Li 2 with (CF3SO3)Cu or (CF3SO 3)Ag (1:2) afford novel hexanuclear cluster compounds of the type Ar4M4M′2(CF3SO 3)2.
UR - http://www.scopus.com/inward/record.url?scp=2042530395&partnerID=8YFLogxK
U2 - 10.1039/C39770000203
DO - 10.1039/C39770000203
M3 - Article
AN - SCOPUS:2042530395
SN - 0022-4936
SP - 203
EP - 204
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -