Influence of Zn concentration in the activity of Cd1-xZnxS solid solutions for water splitting under visible light

F. del Valle, A. Ishikawa, K. Domen, J. A. Villoria de la Mano, M. Calderón De La Barca Sánchez, I. D. González, Sara Herreras Martinez, N. Mota, M. E. Rivas, M. C. Álvarez Galván, J. L. G. Fierro, R. M. Navarro*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

Solid solutions Cd1-xZnxS with different Zn concentration (0.2 < x < 0.35) are investigated in the production of hydrogen from aqueous solutions containing SO3 2-/S2- as sacrificial reagents under visible light. Textural, structural and surface catalyst properties are determined by N2 adsorption isotherms, UV-vis spectroscopy, SEM and XRD and related to the activity results in hydrogen production from water splitting under visible light irradiation. It is found that the crystallinity and energy band structure of the Cd1-xZnxS solid solutions depend on their Zn atomic concentration. The hydrogen production rate is found to increase gradually when the Zn concentration on photocatalysts increases from 0.2 to 0.3. Subsequent increase in the Zn fraction up to 0.35 leads to lower hydrogen production. Variation in photoactivity is analyzed in terms of changes in crystallinity, level of conduction band and light absorption ability of Cd1-xZnxS solid solutions derived from their Zn atomic concentration.

Original languageEnglish
Pages (from-to)51-56
Number of pages6
JournalCatalysis Today
Volume143
Issue number1-2
DOIs
Publication statusPublished - 15 May 2009
Externally publishedYes

Keywords

  • Cadmium sulfide
  • Hydrogen
  • Photocatalyst
  • Solid solutions
  • Water splitting
  • Zinc sulfide

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