In situ XAS of the solvothermal decomposition of dithiocarbamate complexes

H.-U. Islam; A. Roffey; N. Hollingsworth; R. Catlow; M. Wolthers; N.H. de Leeuw; W. Bras; G. Sankar; G. Hogarth

doi:10.1088/1742-6596/430/1/012050

In situ XAS of the solvothermal decomposition of dithiocarbamate complexes

H.-U. Islam
, A. Roffey
, N. Hollingsworth
, R. Catlow
, M. Wolthers
, N.H. de Leeuw
, W. Bras
, G. Sankar
, G. Hogarth

extern

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

An in situ XAS study of the solvothermal decomposition of iron and nickel dithiocarbamate complexes was performed in order to gain understanding of the decomposition mechanisms. This work has given insight into the steps involved in the decomposition, showing variation in reaction pathways between the iron and nickel dithiocarbamates, and the non-innocent role of oleylamine as the solvent and capping agent in the reaction.

Original language	English
Pages (from-to)	012050/1-012050/4
Number of pages	4
Journal	Journal of Physics: Conference Series
Volume	430
DOIs	https://doi.org/10.1088/1742-6596/430/1/012050
Publication status	Published - 22 Jul 2012

Bibliographical note

15th International Conference on X-Ray Absorption Fine Structure, XAFS 2012, Beijing, China

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10.1088/1742-6596/430/1/012050

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abstract = "An in situ XAS study of the solvothermal decomposition of iron and nickel dithiocarbamate complexes was performed in order to gain understanding of the decomposition mechanisms. This work has given insight into the steps involved in the decomposition, showing variation in reaction pathways between the iron and nickel dithiocarbamates, and the non-innocent role of oleylamine as the solvent and capping agent in the reaction.",

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T1 - In situ XAS of the solvothermal decomposition of dithiocarbamate complexes

AU - Islam, H.-U.

AU - Roffey, A.

AU - Hollingsworth, N.

AU - Catlow, R.

AU - Wolthers, M.

AU - de Leeuw, N.H.

AU - Bras, W.

AU - Sankar, G.

AU - Hogarth, G.

N1 - 15th International Conference on X-Ray Absorption Fine Structure, XAFS 2012, Beijing, China

PY - 2012/7/22

Y1 - 2012/7/22

N2 - An in situ XAS study of the solvothermal decomposition of iron and nickel dithiocarbamate complexes was performed in order to gain understanding of the decomposition mechanisms. This work has given insight into the steps involved in the decomposition, showing variation in reaction pathways between the iron and nickel dithiocarbamates, and the non-innocent role of oleylamine as the solvent and capping agent in the reaction.

AB - An in situ XAS study of the solvothermal decomposition of iron and nickel dithiocarbamate complexes was performed in order to gain understanding of the decomposition mechanisms. This work has given insight into the steps involved in the decomposition, showing variation in reaction pathways between the iron and nickel dithiocarbamates, and the non-innocent role of oleylamine as the solvent and capping agent in the reaction.

U2 - 10.1088/1742-6596/430/1/012050

DO - 10.1088/1742-6596/430/1/012050

M3 - Article

SN - 1742-6588

VL - 430

SP - 012050/1-012050/4

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

ER -

In situ XAS of the solvothermal decomposition of dithiocarbamate complexes

Abstract

Bibliographical note

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