TY - JOUR
T1 - In-situ nano-scale investigation of step retreat on fluoranthene crystal surfaces
AU - Giese, C.C.
AU - King, H.E.
AU - van den Ende, M.P.A.
AU - Plümper, O.
AU - ten Kate, I.L.
AU - Tielens, A.G.G.M.
PY - 2018
Y1 - 2018
N2 - Fluoranthene, a polycyclic aromatic hydrocarbon, has been detected on Earth as well as in asteroids and meteorites and may have played a role in the formation of life. Increasing the ionic strength of aqueous solutions has been observed to lower the fluoranthene solubility, but it is unclear how solution composition controls the release rate of fluoranthene to an aqueous solution. To elucidate this, we performed in situ atomic force microscopy experiments in which we characterized the sublimation and dissolution behavior of fluoranthene crystal surfaces. From this, we quantify the step retreat rate upon exposure to air, deionized water, and a 0.4 M NaCl or 0.1 M MgSO4 solution. Surface roughness is the main factor that determines the dissolution or sublimation rate. The results imply that during fluoranthene remediation or breakdown in meteorites and asteroids, ionic strength will be more important than chemical composition for controlling fluoranthene release into solution.
AB - Fluoranthene, a polycyclic aromatic hydrocarbon, has been detected on Earth as well as in asteroids and meteorites and may have played a role in the formation of life. Increasing the ionic strength of aqueous solutions has been observed to lower the fluoranthene solubility, but it is unclear how solution composition controls the release rate of fluoranthene to an aqueous solution. To elucidate this, we performed in situ atomic force microscopy experiments in which we characterized the sublimation and dissolution behavior of fluoranthene crystal surfaces. From this, we quantify the step retreat rate upon exposure to air, deionized water, and a 0.4 M NaCl or 0.1 M MgSO4 solution. Surface roughness is the main factor that determines the dissolution or sublimation rate. The results imply that during fluoranthene remediation or breakdown in meteorites and asteroids, ionic strength will be more important than chemical composition for controlling fluoranthene release into solution.
KW - polycyclic aromatic hydrocarbons
KW - atomic force microscopy
KW - sublimation
KW - dissolution
KW - aqueous solutions
U2 - 10.1021/acsearthspacechem.8b00120
DO - 10.1021/acsearthspacechem.8b00120
M3 - Article
SN - 2472-3452
VL - 2
SP - 1301
EP - 1311
JO - ACS Earth and Space Chemistry
JF - ACS Earth and Space Chemistry
IS - 12
ER -