Hydrogen microstructure in hydrogenated amorphous silicon

J. Daey Ouwens, R.E.I. Schropp

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

We present a method to determine the local hydrogen bonding structure in hydrogenated amorphous silicon from infrared spectroscopy measurements. This approach is based on a different oscillator strength and refractive index for hydrogen atoms located in the isolated and clustered phase. It is demonstrated that the density of distributed hydrogen atoms does not exceed 3-4 at.%, independent of the deposition conditions for several deposition techniques. We suggest that changes in the infrared-absorption strength upon ion bombardment or light soaking can be attributed to a hydrogen exchange between clustered and isolated phases.
Original languageEnglish
Pages (from-to)759-762
Number of pages4
JournalPhysical review. B, condensed matter
Volume54
Issue number24
DOIs
Publication statusPublished - 1996

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